[MoO2Cl2] as catalyst for hydrosilylation of aldehydes and ketones.
نویسندگان
چکیده
The high valent molybdenum-dioxo complex [MoO2Cl2] catalyzes the addition of dimethylphenylsilane to aldehydes and ketones to afford the corresponding dimethylphenylsilyl ethers in quantitative yield.
منابع مشابه
Dioxomolybdenum(VI) complexes as catalysts for the hydrosilylation of aldehydes and ketones.
The dioxomolybdenum(VI) complexes [MoO2Cl2] (1), [MoO2(acac)2] (2), [MoO2(S2CNEt2)2] (3), [CpMoO2Cl] (4), [MoO2(mes)2] (5) and the polymeric organotin-oxomolybdates [(R3Sn)2MoO4] [R = n-Bu (6), t-Bu (7), Me (8)] were examined as catalysts for the hydrosilylation of aldehydes and ketones with dimethylphenylsilane. Of these, [MoO2Cl2] (1) was the most efficient catalyst, affording quantitative yi...
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ورودعنوان ژورنال:
- Chemical communications
دوره 2 شماره
صفحات -
تاریخ انتشار 2005